Abstract

In the title compound, [Cu(C18H16F4N2O2)(H2O)], the CuII atom shows a distorted square-pyramidal coordination geometry with the N,N′,O,O′-tetra­dentate piperazine–diphenolate ligand forming the basal plane. The apical site is occupied by the O atom of a coordinated water mol­ecule. Neighbouring complexes are associated through inter­molecular O—H⋯O and O—H⋯F hydrogen bonds between the water mol­ecule and a phenolate O atom or an F atom from an adjacent ligand, respectively, forming a centrosymmetric dimer. Dimers are linked by additional inter­molecular C—H⋯O and C—H⋯F hydrogen bonds, giving infinite chains propagating along the a axis.

Highlights

  • In the title compound, [Cu(C18H16F4N2O2)(H2O)], the Cu atom shows a distorted square-pyramidal coordination geometry with the N,N0,O,O0 -tetradentate piperazine–diphenolate ligand forming the basal plane

  • The apical site is occupied by the O atom of a coordinated water molecule

  • Neighbouring complexes are associated through intermolecular O—H O and O—H F hydrogen bonds between the water molecule and a phenolate O atom or an F atom from an adjacent ligand, respectively, forming a centrosymmetric dimer

Read more

Summary

Data collection

Division of Natural Sciences, Osaka Kyoiku University, Kashiwara, Osaka 582-8582, Japan. H atoms treated by a mixture of independent and constrained refinement max = 0.54 e Å3. R factor = 0.039; wR factor = 0.108; data-to-parameter ratio = 15.3. In the title compound, [Cu(C18H16F4N2O2)(H2O)], the Cu atom shows a distorted square-pyramidal coordination geometry with the N,N0 ,O,O0 -tetradentate piperazine–diphenolate ligand forming the basal plane. The apical site is occupied by the O atom of a coordinated water molecule. Neighbouring complexes are associated through intermolecular O—H O and O—H F hydrogen bonds between the water molecule and a phenolate O atom or an F atom from an adjacent ligand, respectively, forming a centrosymmetric dimer. Dimers are linked by additional intermolecular C—. H O and C—H F hydrogen bonds, giving infinite chains propagating along the a axis

Related literature
Special details
Full Text
Paper version not known

Talk to us

Join us for a 30 min session where you can share your feedback and ask us any queries you have

Schedule a call