Abstract
In the title compound, [Cu(C18H16F4N2O2)(H2O)], the CuII atom shows a distorted square-pyramidal coordination geometry with the N,N′,O,O′-tetradentate piperazine–diphenolate ligand forming the basal plane. The apical site is occupied by the O atom of a coordinated water molecule. Neighbouring complexes are associated through intermolecular O—H⋯O and O—H⋯F hydrogen bonds between the water molecule and a phenolate O atom or an F atom from an adjacent ligand, respectively, forming a centrosymmetric dimer. Dimers are linked by additional intermolecular C—H⋯O and C—H⋯F hydrogen bonds, giving infinite chains propagating along the a axis.
Highlights
In the title compound, [Cu(C18H16F4N2O2)(H2O)], the Cu atom shows a distorted square-pyramidal coordination geometry with the N,N0,O,O0 -tetradentate piperazine–diphenolate ligand forming the basal plane
The apical site is occupied by the O atom of a coordinated water molecule
Neighbouring complexes are associated through intermolecular O—H O and O—H F hydrogen bonds between the water molecule and a phenolate O atom or an F atom from an adjacent ligand, respectively, forming a centrosymmetric dimer
Summary
Division of Natural Sciences, Osaka Kyoiku University, Kashiwara, Osaka 582-8582, Japan. H atoms treated by a mixture of independent and constrained refinement max = 0.54 e Å3. R factor = 0.039; wR factor = 0.108; data-to-parameter ratio = 15.3. In the title compound, [Cu(C18H16F4N2O2)(H2O)], the Cu atom shows a distorted square-pyramidal coordination geometry with the N,N0 ,O,O0 -tetradentate piperazine–diphenolate ligand forming the basal plane. The apical site is occupied by the O atom of a coordinated water molecule. Neighbouring complexes are associated through intermolecular O—H O and O—H F hydrogen bonds between the water molecule and a phenolate O atom or an F atom from an adjacent ligand, respectively, forming a centrosymmetric dimer. Dimers are linked by additional intermolecular C—. H O and C—H F hydrogen bonds, giving infinite chains propagating along the a axis
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