Abstract

In the title complex, [Cu(C5H5N2O2)(C14H18N3O)(H2O)]·1.33H2O, the CuII ion is coordinated in a slightly distorted square-pyramidal environment. The basal plane is formed by two N atoms from a 2-(5-ethyl-2-pyridyl-κN)-4-isopropyl-4-methyl-5-oxo-4,5-dihydroxy­imidazol-1-ide ligand and by one O atom and one N atom from a 5-methyl-1H-pyrazole-3-carboxyl­ate ligand. The apical position is occupied by a water mol­ecule. In the crystal structure, O—H⋯O, O—H⋯N and N—H⋯O hydrogen bonds lead to a three-dimensional supra­molecular network.

Highlights

  • In the title complex, [Cu(C5H5N2O2)(C14H18N3O)(H2O)]1.33H2O, the CuII ion is coordinated in a slightly distorted square-pyramidal environment

  • The basal plane is formed by two N atoms from a 2-(5-ethyl-2-pyridyl-N)-4-isopropyl-4methyl-5-oxo-4,5-dihydroxyimidazol-1-ide ligand and by one

  • The apical position is occupied by a water molecule

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Summary

Bruker APEXII CCD diffractometer

N—H O hydrogen bonds lead to a three-dimensional supramolecular network

Related literature
Graphite monochromator φ and ω scans
Full Text
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