Abstract
The title CoII complex, [Co(C6H6N4S2)(C4H4O4S)(H2O)]·2H2O, assumes a distorted octahedral coordination geometry formed by a diaminobithiazole (DABT) ligand, a thiodiacetate dianion (TDA) and a water molecule. The TDA dianion chelates to the CoII atom with a facial configuration. Within the chelating DABT ligand, the two thiazole rings are twisted with respect to each other [dihedral angle = 12.04 (9)°].
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