Abstract
The title ZnII complex, [Zn(C4H4O5)(C6H6N4S2)(H2O)]·2H2O, with ligands consisting of an oxydiacetate dianion (ODA), a diaminobithiazole (DABT) molecule and a water molecule, displays a distorted octahedral coordination geometry. The tridentate ODA chelates to the ZnII in a meridional configuration, with the Zn—O(ether) distance of 2.216 (5) Å, much longer than the Zn—O(carboxyl) distances of 2.051 (5) and 2.071 (5) Å. The overlapped arrangement of parallel DABT ligands, with a separation of 3.509 (9) Å between neighboring DABT rings, suggests π–π stacking between neighboring molecules.
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More From: Acta Crystallographica Section E Structure Reports Online
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