Abstract
In the asymmetric unit of the crystal structure of the title compound, [Zn(C3H2O4)(C6H6N4S2)(H2O)]·H2O, there are two independent ZnII complex molecules. Each ZnII ion assumes a distorted square-pyramidal coordination geometry formed by a diaminobithiazole (DABT) ligand, a malonate dianion and a water molecule. Within the chelating DABT ligand, the two thiazole rings are twisted with respect to each other, with dihedral angles of 3.23 (19) and 2.54 (18)°. O—H⋯O and N—H⋯O hydrogen bonding occurs in the crystal structure.
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