Applying Raman Spectroscopy to Modern and Palaeocharcoals Associated with Wildfire Activity

Abstract

<p>Evidence of wildfire activity in deep time is preserved in the rock record as fossilised charcoal. Modern wildfire temperature is often a function of fuel type, structure and availability. These three factors are reliant upon climatic conditions and offer a potential insight into palaeoenvironmental conditions through geothermometric analysis of preserved charcoals. Much like the analysis of vitrinite reflectance as an assessor of thermal maturity, similar methodology has been applied historically to charcoal in order to obtain palaeowildfire temperatures.  Raman spectroscopy has similarly been applied to organic material as an identifier of thermal maturity, via the analysis of carbon microstructure changes with increasing temperature – however very little palaeocharcoal has been analysed via Raman spectroscopy, with no apparent application to palaeowildfire geothermometry. Through the application of Raman spectroscopy, we present the first comparison of modern pyrolyzed plant material with spectra of early Danian palaeocharcoals, associated with wildfire activity. These results indicate that Raman spectroscopy of modern wildfire charcoal facilitates a correlation between charcoal microstructure change and temperature of formation. This in turn has enabled comparison with palaeocharcoal, and the generation of reliable wildfire geothermometry. With this new methodology, we intend to further the understanding of (1) changes in palaeowildfire regimes and intensity through time (2) the interaction between climate, plant community composition and structure, and palaeowildfires  (3) correlation and comparison with existing palaeowildfire interpretive approaches. Further analysis and experimentation is required to identify the impact of fire determining factors on observed spectra to target the new approach towards interpreting current and future wildfire behaviour under climatic stress. </p>