Applying isovolumic steam capsule as new thermal energy storage unit

Abstract

In order to make up the inefficiencies of liquid–solid phase change material (PCM) such as low latent heat and low heat transfer rate, the possibility of adopting water steam as the phase change material is explored. Although great volume change occurs during the gas–liquid phase-changing, the specific latent heat is at least one order of magnitude larger than that of liquid–solid phase-changing. To minimize the adverse effect of the great volume change during vaporization or condensation, the steam can be accommodated inside sealed vessel with sturdy shell. In this study, an isovolumic steam capsule (ISC) was made by filling a cylinder with a small amount of liquid water and then heated and boiled to extinguish the non-condensable gas (NCG) before sealing it. Thermodynamic analysis shows the thermal energy contained in the isovolumic steam capsule per unit volume increases in approximately an exponential manner with the increase of temperature due to the evaporation of liquid, and can reach several times that of liquid–solid phase change material, demonstrating great potential as energy storage material. The heat transfer experiments show that the energy charging and discharging rates increase with the temperature difference. There exists thermodynamic non-equilibrium during heat transfer and the deviation from saturation enlarges with increasing temperature difference and non-condensable gas concentration. For both charging (vaporization) and discharging (condensation), a higher non-condensable gas concentration in the steam exhibits larger heat transfer rate in the beginning, but smaller heat transfer rate in the later stage. The mechanism of vaporization and condensation in the isovolumic steam capsule awaits to be further clarified.