Appling fluorescence spectroscopy with absolute principal component coefficient to explore dynamic migration of DOM fractions from an urbanized river during torrential rainfall

Abstract

This research delves into the dynamic interplay between urbanization and the characteristics of Dissolved Organic Matter (DOM) in the Anyang River, particularly under the stress of torrential rain. The motivation stems from a critical need to decipher how urban landscapes influence water quality, focusing on the intricate transformations and movements of DOM. Employing advanced fluorescence spectroscopy techniques like Excitation-Emission Matrices (EEM) and Parallel Factor Analysis (PARAFAC), the study meticulously differentiates DOM compositions in urban and agricultural settings. It unveils a pronounced distinction, with urban streams showing elevated proteinaceous DOM from wastewater, contrasting with the humic substances prevalent in agricultural runoff. The analysis also captures how intense rainfall events catalyze significant shifts in DOM profiles, thereby emphasizing the need for tailored water quality management strategies in urbanized catchments. This comprehensive approach not only bridges gaps in understanding the urban impact on riverine ecosystems but also sets a foundation for future research and policy development in the face of escalating environmental changes.