Abstract

Typical applications of high resolution Zero kinetic energy (ZEKE) photoelectron spectroscopy to molecules and clusters are reviewed. The high resolution of ZEKE spectroscopy compared to conventional photoelectron spectroscopy allows the rotational structure of larger molecular cations, for instance the benzene cation, to be obtained. The dynamic Jahn-Teller effect and the shape of the benzene cation is apparent from these rotationally resolved ZEKE spectra. For molecular clusters, the phenol-water and phenol-methanol complexes show dense, clearly resolved intermolecular vibrations.

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