Applications of SBA-15 supported Pd metal catalysts as nanoreactors in C-C coupling reactions.

Abstract

Nanoreactors are material structures with engineered internal cavities which create exclusive confined nanoscale surroundings for chemical reactions. The cavities of mesoporous silica SBA-15 can be used as nanoreactors for incorporating catalytic species such as metal nanoparticles, complexes etc. Since SBA-15 silica has a neutral framework, organic functional groups and heteroatoms have been embedded by direct or post-synthesis approaches in order to modify their functionality. Palladium is the most used transition metal for C–C bond formations. Because of the great importance of C–C coupling reactions, this review article aims at providing a deep insight into the state of art in the field of the synthesis and the application of mesoporous SBA-15 silica-supported Pd catalysts in C–C coupling transformations. In most cases, synthesis and modification of the catalyst, time and yield of reactions, recyclability and leaching of the Pd species from the SBA-15 support are discussed to reveal the role of SBA-15 in C–C coupling reactions.