Abstract

In recent years nuclear magnetic resonance (NMR) sensors have been increasingly applied to investigate, characterize and monitor objects of cultural heritage interest. NMR is not confined to a few specific applications, but rather its use can be successfully extended to a wide number of different cultural heritage issues. A breakthrough has surely been the recent development of portable NMR sensors which can be applied in situ for non-destructive and non-invasive investigations. In this paper three studies illustrating the potential of NMR sensors in this field of research are reported.

Highlights

  • Laboratorio di Risonanza Magnetica “Annalaura Segre”, Istituto di Metodologie Chimiche, CNR Area della Ricerca di Roma 1, Via Salaria Km 29,300, 00015 Monterotondo (Rome), Italy; Tel.: +39-06-906-72-700; Fax: +39-06-906-72-519

  • Results obtained by 13C-CPMAS nuclear magnetic resonance (NMR) spectroscopy allowed the identification of the wood of the icon as a hardwood, indicated a loss of lignin component in the investigated region, and the occurrence of chemical rearrangements in lignin structure caused by degradation

  • The three cases reported, though not exhaustive, demonstrate that NMR applications can be successfully extended to different issues regarding cultural heritage

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Summary

Basic of NMR Sensors

Nuclear magnetic resonance (NMR) is a powerful tool in many fields and a diversity of NMR measurements and methodologies have been and are currently being exploited. A further development of unilateral NMR devices are sensors that can scan depths up to 2.5 cm, producing depth profiles with micrometric spatial resolution [26] These devices generate an inhomogeneous magnetic field with a uniform gradient to resolve the near surface structure of arbitrarily large samples. Application of these devices has opened a number of new possibilities in the field of cultural heritage [27,28,29,30,31,32,33,34]. In the following we report three cases illustrating the potential of NMR sensors in cultural heritage

Quantitative Moisture Distribution Mapping in an Ancient Wall Painting
NMR Stratigraphy of a Painting on Wooden Panel
NMR Investigation of a Consolidating Treatment on a Porous Stone
Conclusions
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