Abstract
This account covers the recent advance of the dual-mode Lewis acid induced cascade cyclization reactions in our group. Taking advantage of the special properties of the dual-mode Lewis acids, three new types of cascade reactions have been developed. Moreover, the applicability of the cascade cyclization reactions was explored through studying the scope of substrates. Finally, these reactions were employed for total syntheses of natural products. Keywords dual-mode Lewis acid; cascade cyclization reaction; total syntheses of natural product
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