Applications of carbide ceramics in nuclear reactors

Abstract

<p indent=0mm>After the Fukushima nuclear accident in Japan, the safety requirements of nuclear energy systems are constantly increasing. A series of new nuclear energy systems are under development, such as very high-temperature gas-cooled reactor (VHTR), lead-cooled fast reactor (LFR), gas-cooled fast reactor (GFR) and so on. In order to achieve the goals of higher safety, these nuclear systems have put forward higher requirements for nuclear materials. For example, materials working in VHTR and GFR are supposed to withstand higher temperatures, and LFR requires materials to be more corrosion-resistant. Nuclear materials have to meet these requirements under normal operating conditions, as well as in incidental and accidental conditions. Therefore, it is necessary to optimize the existing material system and develop new high-performance materials to meet the future development needs of advanced nuclear power systems. Compared with traditional nuclear materials, carbide ceramics have better mechanical properties under elevated temperatures, stronger irradiation resistance and better comprehensive thermophysical properties. Up to now, great breakthroughs have been made in the research of carbide ceramic materials and some key materials are going to be used in the new-generation nuclear systems. For example, uranium carbide (UC) is gradually replacing traditional uranium dioxide (UO₂), and silicon carbide (SiC) is acting as the main fission product barrier layer of coated fuel particles in HTGR. Other new carbide materials such as zirconium carbide (ZrC) and MAX phase carbide materials are also becoming a new research hotspot in the field of nuclear materials. Compared with other ceramic materials, the fabrication especially its densification of carbide is generally more difficult. In addition, high purity and good neutron properties are also the basic requirements of carbide ceramic materials for nuclear energy. The vapor deposition process and powder metallurgy process have been used to fabricate carbide ceramics for different components in nuclear reactors. Some new preparation methods have been developed to fabricate fuels and structural materials. For example, gelation progress is applied to prepare UCO microsphere fuel, and nano infiltration and transient eutectic (NITE) process is used in the preparation of SiC_f/SiC composites, which is potential for nuclear claddings. The irradiation-induced degradation of nuclear ceramic materials in the reactor is unavoidable. In order to evaluate the performance changes of materials under irradiation conditions, different irradiation methods such as electron irradiation, ion irradiation, proton irradiation and neutron irradiation are used. Due to its unique microstructure and properties, carbide ceramics exhibit different properties from other nuclear materials under irradiation. The performance changes of main nuclear carbide materials after irradiation are summarized, including microstructure evolution, macroscopic irradiation-induced swelling, changes in mechanical and thermal properties, etc. In general, based on the current research progress, the article reviews the application of carbide ceramics in new nuclear power systems and elaborates their service scenarios. Basic properties, preparation methods and irradiation properties of carbide ceramic materials are introduced in detail. The future development directions and the processing techniques are proposed. In the future, carbide ceramic materials should be further developed, and carbide ceramic materials will find diverse applications in the new generation nuclear systems.