Application of ZnO micro rods on the composite photo-electrode of dye sensitized solar cells

Abstract

In this study, we prepared low-density ZnO micron rods (MRs) on ITO/PEN substrate by hydrothermal method, and used the scraper to fill the ZnO nanoparticles into the micron rods to prepare ZnO composite structure as the photo-electrode of dye sensitized solar cells (DSSCs). The nanostructures and photo-electrodes were investigated by field emission scanning electron microscopy (FE-SEM), electrochemical impedance spectroscopy (EIS), incident photon conversion efficiency (IPCE) and I–V characteristics analyses. In the results of FE-SEM, they show that the average length of the ZnO MRs and the thickness of ZnO film are 14 and 33.1 μm, respectively. EIS analyses show that there is a minimal RK and the longest electron lifetime of DSSCs with the ZnO composite structure, which means less recombination of the electrons in the ZnO composite structure. The results of IPCE indicate that the photo-electrode of ZnO composite structure exhibits the best quantum efficiency about 81.7%. It may be due to ZnO MRs play as a light scattering layer resulting in the increase of path length for the incident light, thereby increasing the collision probability between the incident light and the ZnO nanoparticles. In addition, we also compared the I–V characteristics of three different photo-electrodes with ZnO NPs, ZnO NPs pressed 418.8 kg/cm2 and ZnO composite structure. The best structure is ZnO composite structure, and it has the best current density (JSC = 10.59 mA/cm2) and overall conversion efficiency (η = 3.46%) of dye-sensitized solar cells.