Application of water quality control charts to spring monitoring in karst terranes

Abstract

Presence of springs in karst terranes provides a unique opportunity to study the rather complex, multi-porosity, and multi-permeability system. When springs are used to evaluate the integrity of storage facilities for hazardous materials or waste disposal facilities constructed in karst areas, the spatial heterogeneity of karst aquifers makes intra-spring comparisons preferred statistical tests. One of the commonly used statistical tests is water quality control procedure such as Shewhart-CUSUM control charts. Appropriate application of the water quality control procedure to intra-spring monitoring depends on whether the assumptions can be justified about the aquifer that drains to the spring and the dataset collected at the spring. Violation of the assumptions would render the statistical tests invalid, which may result in a failure of the groundwater monitoring program. In intra-spring monitoring, it is the temporal variations of water quality at a karst spring need to be addressed, whereas the water quality at the spring is closely associated with the characteristics of the aquifer. The example datasets presented in the paper indicate that both false negative and false positive detections can occur if the temporal variation is not well characterized.