Application of the spectral correction method and “neural networks” for simultaneous determination of V(V) and Al(III)

Abstract

Simultaneous determination of V(V) and Al(III) was performed by application of neural networks when the calibration matrix was performed using β-correction spectra. Two reactions between V(V) and Al(III) and Alizarin Red S (ARS) as a ligand have been investigated and applied for the simultaneous spectrophotometric determination of these metal ions. The parameters controlling behavior of the system were investigated and optimum conditions selected. Feed-forward neural networks have been trained to quantify considered metal ions in mixtures under optimum conditions. Sigmoidal functions were used in the hidden and output layers. Determinations were made over the concentration range 0.10–7.80 μg ml −1 of V(V) and 0.11–4.20 μg ml −1 of Al(III). Applying this method satisfactorily to simultaneous determination of these metal ions in several synthetic solutions with total relative standard error less than 4.02% validated the proposed method.