Abstract

The potential of the semiclassical approximation for the description of real radical pairs with non-equivalent nuclei has been investigated. The relation between the CIDNP field dependence of a given nucleus and the hfi constant of the partner radical has been studied. It is shown that the semiclassical approximation is applicable to multinuclear radical pairs even if there are only a small number of equivalent nuclei ( n=2, 3), provided that the hfi constants of these nuclei are prevalent.

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