Abstract
Excess molar volumes of binary mixtures of (acetonitrile + 1-heptanol or 1-octanol) as a function of composition under atmospheric pressure and at 293.15, 298.15 and 313.15 K have been used to test the applicability of the Prigogine-Flory-Patterson theory. Both systems exhibit positive V m E values over the whole mole fraction range in the temperature range studied. The agreement between theoretical and experimental results is satisfactory for the studied systems.
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