Abstract
The Prigogine-Flory-Patterson theory of liquid mixtures has been applied to the HmE and VmE for binary mixtures of an n-alkane with decalin, bicyclohexyl, tetralin, cyclohexylbenzene, benzene, cyclohexane and n-hexane with 1-hexene, 1-hexyne, 1-heptene and 1-heptyne. Furthermore the Prigogine-Flory theory has been used to predict activity coefficients at infinite dilution from the experimentally determined HmE at 25°C for the mixtures 1-hexene, 1-hexyne, 1-heptene, 1-heptyne with decalin, bicyclohexyl, tetralin and cyclohexylbenzene. The predictions are compared to experimental results.
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