Application of the Pitzer ion interaction model to isopiestic data for the Fe 2(SO 4) 3–H 2SO 4–H 2O system at 298.15 and 323.15 K

Abstract

Recent isopiestic studies of the Fe 2(SO 4) 3–H 2SO 4–H 2O system at 298.15 K are represented with an extended version of Pitzer’s ion interaction model. The model represents osmotic coefficients for aqueous {(1 − y)Fe 2(SO 4) 3 + yH 2SO 4} mixtures from 0.45 to 3.0 m at 298.15 K and 0.0435 ⩽ y ⩽ 0.9370. In addition, a slightly less accurate representation of a more extended molality range to 5.47 m extends over the same y values, translating to a maximum ionic strength of 45 m. Recent isopiestic data for the system at 323.15 K are represented with the extended Pitzer model over a limited range in molality and solute fraction. These datasets are also represented with the usual “3-parameter” version of Pitzer’s model so that it may be incorporated in geochemical modeling software, but is a slightly less accurate representation of thermodynamic properties for this system. Comparisons made between our ion interaction model and available solubility data display partial agreement for rhomboclase and significant discrepancy for ferricopiapite. The comparisons highlight uncertainty remaining for solubility predictions in this system as well as the need for additional solubility measurements for Fe 3+-bearing sulfate minerals. The resulting Pitzer ion interaction models provide an important step toward an accurate and comprehensive representation of thermodynamic properties in this geochemically important system.