Abstract
The principles of the application of the explicit finite difference simulation method to cyclic voltammetry are described, and the limitations and capabilities of the method are discussed for several examples. The main reactions treated are an e.c. mechanism with the chemical reaction reversible in character, and an e.e. mechanism in which the second reversible charge-transfer competes with a dismutation equilibrium triggered by a subsequent irreversible chemical reaction. Attention is given to the proper notation for use in simulating homogeneous chemical reactions.
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