Application of Synthesized Biomass Bamboo Charcoal–Iron Oxide “BC/Fe” Nanocomposite Adsorbents in the Removal of Cationic Methylene Blue Dye Contaminants from Wastewater by Adsorption

Abstract

In this work, synthesized, raw-bamboo-biomass-based magnetic “BC/Fe” bamboo charcoal–iron oxide nanocomposite adsorbents were characterized and tested for their effects on the removal of aqueous-phase cationic methylene blue (MB) dye pollutants from synthetic wastewater through a laboratory batch adsorption study. This batch adsorption study aimed to identify various physico-chemical process parameters such as initial dye concentration, solution pH, adsorbent dose, temperature, and their effects on the adsorption kinetics and adsorption isotherm characteristics. From the kinetic studies, it was found that the amount of MB dye adsorption by synthesized adsorbents qe (mg/g) increased from 9.50 mg/g to 15.30 mg/g with the increase in the initial dye concentration range of 10 to 30 ppm, as per contact time, but decreased with the increase in the temperature range from 30 to 60 °C and the adsorbent doses from 20 to 40 mg, respectively, under specified experimental process conditions. From the kinetic study, it was also found that equilibrium was reached within 120 min, the adsorption kinetics followed three mechanistic steps, and the pseudo-second-order (PSO) kinetic model was applicable to explain the data of the batch adsorption kinetics. The various kinetic model parameters were determined from a fitted model equation. Furthermore, there was an increase in the amount of the MB dye adsorption qe (mg/g) from 9.87 mg/g to 17.62 mg/g with the increase in the solution pH from 3 to 7, and a reduction in the amount of dye adsorption qe (mg/g) was found at the solution pH of 10 for a 20 ppm MB dye solution at 30 °C. Both the Freundlich and Langmuir isotherm models were applicable to the equilibrium data, and the maximum adsorption capacity from the Langmuir isotherm fitting was 111.11 mg/g, which was comparative to or even better than many other magnetic adsorbents for methylene blue dye adsorption. Finally, the regeneration and reusability of the magnetic “BC/Fe” bamboo charcoal–iron oxide nanocomposite materials as well as the limitations of these batch adsorption studies are also discussed here.