Abstract
The electrochemical behavior of ferrocene in acetonitrile at the platinum|Nafion® interface was investigated using SPE composite microelectrodes. Two parallel reactions take place at the interface. The redox reaction of ferrocene|ferricinium ions predominates at the platinum|Nafion® composite microdisk electrode, while the adsorption or desorption of atomic hydrogen predominates at the platinum black|Nafion® composite powder microelectrode. This fact implies that the electrochemical reactions take place only at the interface and the adsorption of atomic hydrogen can occur on surface sites remote from the interface. The SPE composite microelectrode seems to be a potential technique of investigating the spillover of adsorbed species on the electrode surface.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
