Application of radon (222Rn) as an environmental tracer in hydrogeological and geological investigations: An overview.

Abstract

Radon (222Rn) is a colourless, odourless, inert, and radioactive noble gas (t1/2=3.8 days) that emanates from rocks and soils as a result of the alpha decay of its parent, radium (226Ra) in the decay series of uranium-238, is the focus of this study. Radon is produced in the crystal lattice of the minerals and emanates out through alpha recoil. It dissolves in water, and is also found in soil and air. Its distribution in water is more pertinent for scientific investigations. It can be measured by various methods. Certain properties of radon enable it to serve as an ideal tracer, viz., short-half life, inertness, high abundance in groundwater than surface water, preferential partitioning, sensitivity to sudden changes in subsurface conditions, non-invasiveness etc. This paper reviews the state-of-the-art techniques on the measurement of dissolved radon in water and its potential applications as a tracer and precursor in several hydrogeological and geological applications like understanding the surface water - groundwater interactions, hydrograph separation of streams, estimation of Submarine Groundwater Discharge (SGD), study of hydrodynamics and water balance of lakes, earthquake predictions, locating geological structures (faults/lineaments), geochemical explorations, NAPL contamination studies etc. Among the various applications presented, radon based approach is found to be more reliable in water resources domain than seismic precursory studies. The interpretations based on radon study in the above applications will pave the way for the improved understanding of the hydrological processes, and thus, help the planners and water managers for the sustainable development and management of water resources.