Abstract

Two kinds of quaternary aminated β-cyclodextrin ionic liquids were synthesized and used as stationary phases in capillary gas chromatography. The influences of different counter ions (tetra- borofluoride, bis-trifluoromethanesulfonylimide) were studied. The results indicated that quaternary aminated β-cyclodextrin ionic liquids possessed good column coating properties and a chromatographic separation abilities. The Grobs mixture, alkanes, alcohols and aromatic position isomers, such as xylene, nitrotoluene, dichlorobenzene and cresol were separated well. These quaternary aminated β-cyclodextrin ionic liquids have potential to separate some complex compounds including alcohol, amine, ester etc.

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