Application of petrophysical methods to estimate total organic carbon in Lower Jurassic source rocks from the offshore Lusitanian Basin (Portugal)

Abstract

Lower Jurassic outcrops in the westernmost part of the Lusitanian Basin (São Pedro de Moel area, Portugal) reveal three stratigraphic units with source rock potential: i) Unit F from the Coimbra Formation, ii) the Polvoeira Member of the Água de Madeiros Formation, and iii) the Marly Limestones with Organic-rich Facies Member of the Vale das Fontes Formation. Despite decades of research, these source rocks have not yet been characterised in the offshore areas of the Lusitanian Basin.As a consequence of the discrepancy between organic matter contents in correlative surface-subsurface intervals, this paper investigates the applicability of petrophysical methods to semi-quantitatively estimate total organic carbon (TOC) and delineate source rock intervals in Lower Jurassic (Sinemurian–Pliensbachian) units in the offshore Lusitanian Basin. This study is based on the i) high-resolution stratigraphic correlation between well 14A-1 and the São Pedro de Moel section and ii) calibration of the TOC curve calculated for well 14A-1 using the high-resolution TOC datasets from São Pedro de Moel.Sonic transit time vs resistivity cross-plot shows that several intervals of the aforementioned lithostratigraphic units deviate from the (organic) lean sediment baseline, interpreted to indicate the presence of hydrocarbons and low-density organic matter. Thermal maturity from cuttings samples were used to estimate vitrinite reflectance for each well point measurement. These values vary between 0.51 and 0.87, indicating that the studied interval has reached the oil generation window. The level of organic metamorphism is in accordance with the hydrocarbon generation window interval, varying between 9.49 and 9.76. Neutron/resistivity, density/resistivity, and sonic/resistivity cross-plots and the petrophysical-based method for TOC calculation outlined in Passey et al. (1990) demonstrate the close similarity between TOC curves calculated for well 14A-1 and TOC measurements from the São Pedro de Moel outcrops. This comparison highlights the organic-rich nature of Unit F, the Polvoeira Member and the Marly Limestones with Organic-rich Facies Member in the offshore areas of the Lusitanian Basin and their potential as hydrocarbons source intervals.This work demonstrates a feasible solution to semi-quantitatively estimate TOC in subsurface source rocks when there is large uncertainty regarding sample quality. Delineation of source rock intervals in the offshore wells of the Lusitanian Basin reduces uncertainty, minimises risk, and may aid in new exploration concepts for hydrocarbons offshore Portugal. On a broader scale, this work reinforces the importance of outcrop control to correlate and improve the current knowledge of Portugal's offshore areas.