Abstract
A phosphine sulfide Pd(II) complex, [Pd(p 2S 2) 2](BF 4) 2 ( 1) (p 2S 2 = 1,2-bis(diphenylphosphino)ethane disulfide), was synthesized and characterized by an X-ray crystal structure analysis and 31P NMR spectroscopy. The p 2S 2 ligand exchange rate of 1 with free p 2S 2 in chloroform was revealed to be comparable to the general solvent exchange rate on Pd(II). The catalytic activity of 1 was evaluated by carrying out the Heck reaction. The diminishing of the induction period and acceleration of the reaction were observed for 1 by comparing the phosphine Pd(II) complexes with a leaving chloro ligand, [PdCl(p 3)]Cl (p 3 = bis[2-(diphenylphosphino)ethyl]phenylphosphine) and [PdCl(pp 3)]Cl (pp 3 = tris[2-(diphenylphosphino)ethyl]phosphine), and the catalytic activity was comparable to that of the phosphine Pd(0) complex, [Pd(PPh 3) 4]. Such a high catalytic activity of 1 is attributed to the π-accepting ability of the phosphine sulfide S atom which stabilizes the catalytically active Pd(0) species electronically and weak σ-donation of the S atom which does not block the formation and a subsequent reaction of the Pd(II) substrate adduct in the catalytic cycle.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
