Abstract
Ościk's Equation, assuming the partition displacement model for a chromatographic process is proposed, for the description of solute retention in reversed phase liquid chromatography. Moreover, a numerical method of calculation of solutes retention factors in water, derived from the linear form of this Equation is presented. Theoretical investigations are applied to the literature of the RP HPLC results obtained for a group of model solutes, i.e., alkyl benzene homologues and test substances of different polarities chromatographed using three chemically bonded stationary phases: RP-8 (octylsilyl-silica), ODS (octadecylsilyl-silica) and PLRP-S (polystyrene-divinylbenzene polymer, PS-DVB) and water-methanol and/or water-acetonitrile mixtures as effluents. Calculated chromatographic parameters were analyzed as hydrophobicity indices and related to experimental and calculated log P values.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callMore From: Journal of Liquid Chromatography & Related Technologies
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
