Abstract
Graphic While the most catalysts applying for mimicking of oxygenation function of cytochrome P450 rely on the metalloporphyrins, we present here novel approach based on M n + metallocomplexes of novel ligands: arylmethyl substituted bis-β-aminoketones. The efficacy of catalyst for 1-hexene oxygenation was tested as function of M n + , ligand type and reaction conditions. Our results revealed that the best performance is for Co(II) metallocomplexes of ligand N , N ′-ethylenebis[4-amino-1,5-di-(2-naphthyl)]pent-3-en-2-one are the most efficient for conversion of 1-hexene to oxygenation products. Analysis of product distribution was performed with GC–MS analysis, the mild conditions of analysis allowed to detect primary products of oxygenation reaction.
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