Application of nanoadsorbents for removal of lead from water

Abstract

Enormous increase in the application of various heavy metals including lead for commercial and non-commercial purposes has also led to their enhanced occurrence in the effluents from industries and domestic discharge creating substantial environmental concerns. The existing techniques for removal of these contaminants such as reverse osmosis and ion exchange suffer a few disadvantages and hence, thrust to develop efficient techniques for the removal have been ever increasing. Adsorption based on the use of nanoadsorbents is promising being cost effective and based on the ease of operation. The present work furnishes a detailed overview on nanoadsorbents for removal of lead from water. The various nanoadsorbents covered in the analysis include alumina, anatase, carbon nanotubes, chitosan, copper, iron and zinc oxide, magnetite, nanoclay and zirconium nanoparticles. The review also gives an insight into the synthesis and characterization of nanoadsorbents followed by guidelines on optimum operating parameters to be used in the removal process for maximizing the extent of removal. The typical optimum conditions established based on the critical analysis of literature are pH ≤ 6, contact time ≥60 min and optimum adsorbent dose dependent on the nanomaterials. Comparison of different nanoparticles revealed that titanium oxide and hematite nanoparticles are the best, giving 100% removal efficiency for lead ions. The sequestration was mainly dependent on adsorbent dose that has to be kept optimum to yield adequate surface area and number of adsorption sites. Overall, nanoadsorbents have been established to yield efficient removal of lead from water.