Abstract
)–HMC diacetate, 3 show that zinc is six-coordinate in adistorted octahedral environment bound to four equatorial N atoms from the macrocycle and two axialacetato O atoms. The 14-membered metallo-macrocycle adopts a trans-III (RRSS) configuration with twosix-membered rings in chair forms and two five-membered rings in gauche forms. In the chloridoZn(
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