Application of hydrophilic modified nylon fabric membrane in an anammox-membrane bioreactor: performance and fouling characteristics.

Abstract

The membrane fouling is the main bottleneck hindering the wide applications of anammox-membrane bioreactor (MBR). In this study, surface-coating hydrophilic modification of the membrane using polyvinyl alcohol was applied in a granular anammox-MBR. Stable anammox performance of >77% total nitrogen removal efficiency was achieved in both original and modified MBRs, along with decreasing anammox granule size. The modified membrane exhibited superior flux performance, and the membrane foulants were reduced in the MBR operation. Specifically, the foulant formation rate (f) was 0.46 g·m-2·d-1 for the modified membrane with 100-μm coating thickness (M100) compared with 0.75 g·m-2·d-1 for the original membrane (M0). However, the fouling cycle of the modified membrane with 250-μm coating thickness (M250) was greatly shortened (5 days compared with 19 days for M0) and f increased to 1.25 g·m-2·d-1. Specially, the excess adhesion of exopolysaccharides and humic substances to the hydrophilic modified membrane changed the fouling layer structure and filtration resistance distribution, ultimately causing higher filtration resistance when coating thickness increased. Notably, the flux decline contribution of the concentration polarization was only 33.3% for M0, while it was 71.3% for M250. Finally, it was revealed that using a modified membrane increased the biological secretion rate of polysaccharide but decreased the protein bio-production rate, leading to a high PS (polysaccharide)/PN (protein) ratio in the MBR. The fouling mechanism of the hydrophilic modified membrane applied in anammox-MBR was proposed, and we highlight that the degree of hydrophilic modification is crucial to mitigating membrane fouling.