Abstract

Polyacrylate polymer (PA) was modified with graphene oxide (GO) and the obtained composites were applied as coatings for controlled-release coated urea (CRU). The physicochemical properties of the different PA/GO coatings were characterized in detail and the nitrogen-release characteristics of the obtained CRU samples were determined in water at 25 °C. The experimental results revealed that addition of GO to PA reduced the swelling degree from 83.01% to 46.35% and improved its mechanical properties (the Young’s modulus was improved from 31.52 to 34.97 MPa and the glass transition temperature was increased from 4.21 to 6.11 °C), thus dramatically slowing down the cumulative nutrient release from the CRU fertilizer from 87.25% to 59.71%. These results suggest that GO enhances the properties of PA for CRU applications, which shows that GO-modified PA is a good coating material.

Highlights

  • With the rapid population growth, the demand for grain production has raised significantly.In order to satisfy the food needs of our ever-growing population, the development of modern mechanical agriculture techniques and the extensive use of chemical fertilizers and pesticides are key

  • By comparing the two different dispersions, one can observe the differences in color with the increasing amount of graphene oxide (GO)

  • The dispersion 1 observe the differences in color with the increasing amount of GO

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Summary

Introduction

With the rapid population growth, the demand for grain production has raised significantly. In order to satisfy the food needs of our ever-growing population, the development of modern mechanical agriculture techniques and the extensive use of chemical fertilizers and pesticides are key. Fan and Pardey [1] have suggested that 21.7% of the agriculture production growth in China from 1965 to 1993 resulted from the increasing use of fertilizers. Because of the low use efficiency of N and the maximum use of nitrogen fertilizer, the use of urea poses a dilemma. To increase the efficient use of urea and minimize its negative impact on the environment, controlled-release fertilizers have been proposed as one of the solutions [8,9]

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