Application of chitosan-alginate bio composite for adsorption of malathion from wastewater: Characterization and response surface methodology

Abstract

Agricultural effluents in aqueous media have caused serious threats due to adversely affect human health and the ecosystem. In this study, the low-cost easily accessible chitosan-alginate adsorbent was prepared for the removal of malathion from agricultural effluents using microemulsion method. The adsorbent was characterized using scanning electron microscopy (SEM), Brunauer–Emmett–Teller (BET), X-ray diffraction (XRD), and Fourier-transform infrared spectroscopy (FTIR). The optimum experimental conditions, including adsorbent dosage (0.05–0.25 g), contact time (5–25 min), and concentration of malathion (5–25 mg L−1) at five levels were studied using the composite central design (CCD) based on the response surface methodology (RSM). The highest removal percentage was obtained 82.35 with an adsorbent dosage of 0.18 g, contact time of 20 min, and initial concentration of 10 mg L−1. The analysis of variance (ANOVA) was applied to assess the significance and adequacy of the model. The results revealed that quadratic model was proper for the prediction removal of malathion. The adsorption kinetics and isotherms were examined under optimal conditions. The Langmuir with a coefficient of determination (R2) = 0.99 and pseudo-second-order with R2 = 0.99 were achieved as the best isotherm and kinetic models, respectively. The results showed that the chitosan-alginate biopolymer can be effective and affordable adsorbent for the removal of malathion from aqueous solution.