Abstract
Asymmetric functionalisation of tricarbonylchromium(0) complexes of benzyl alkyl ethers using a dilithiated chiral amide base is the key step in a short and versatile synthesis of planar chiral (arene)tricarbonylchromium(0) complexes. The synthesis of four complexes of potential use in asymmetric catalysis is described herein together with the first demonstration that the asymmetric functionalisation mediated by this chiral base may be used to introduce phosphine substituents.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
