Abstract
Efficient oil separation is the most desirable, but still challenging solution for the waste crude oil problem. This study developed biosurfactant surfactin as a novel pH-switchable biodemulsifier for efficient oil separation. As found, surfactin demulsification achieved a quite well oil separation ratio of over 95% on model emulsions after 20 min at 50 °C. The validity of this demulsification process should be mainly based on the readily lost stabilization ability of surfactin in emulsions triggered by acid addition. Then, surfactin (0.2 g/L) treatment with the aid of ethanol (2%) to improve its distribution could recover over 95% of oil from waste crude oil. After treated by surfactin, the separated oil phase contains tiny water (less than 0.5%) and thus can be reused for resource recycling to reach a compromised balance between satisfying the strict environmental regulations and decreasing the high treatment costs. Hence, in consideration of high demulsification efficiency, environmental-friendly properties and cost-efficiency, surfactin has a great potential for industrial applications for oil recovery from waste crude oil which is a severe problem presents in most of the petroleum-related factories.
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