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Abstract
A new equation for gas adsorption on microporous solids is proposed on the basis of the exponential adsorption isotherm, which is generated by the virial expansion of the spreading pressure. Expressions associated with this equation are derived also for the adsorption potential distribution, the differential molar enthalpy, and the differential molar entropy of adsorption. It is shown that this equation gives a good description of benzene adsorption on activated carbons with different degrees of microporosity and structural heterogeneity.
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