Abstract
In the present study, the nickel-catalyzed cross coupling of aryl halides with benzyl zinc bromides or dialkyl zinc reagents to create C(sp 2)–C(sp 3) bonds has been explored. As pre-catalyst the well-defined and easy-accessible (bispidine)Ni(NO3)2 complex has been applied. After investigation of different reaction parameters a broad scope of C(sp 2)–C(sp 3) bond formations were feasible under mild reaction conditions. .
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