Abstract
3,3′-Disubstituted xylBINAP derivatives were applied to inter- and intramolecular asymmetric Heck/Mizoroki reactions. The results from these reactions were compared to those obtained with ( R)-xylBINAP, ( S)-BINAP and 3,3′-disubstituted BINAP derivatives. Catalysts derived from 3,3′-disubstituted xylBINAP ligands were found to be most effective in the arylation of 2,3-dihydrofuran in terms of reaction times, conversions, and product enantioselectivity.
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