Abstract

Galena, sphalerite, and pyrite are important metallic sulfide minerals and are often associated with one another. In the flotation separation of galena-pyrite mixed concentrate, large amounts of lime (CaO) are used for the depression of pyrite. In this study, the negative effects of lime were reduced by using an efficient depressant Na2SO3 + CaO reagent in the flotation separation of galena from pyrite. Real ore sample flotation separation tests showed that the mixed depressant can efficiently depress pyrite from galena-pyrite mixed concentrate. The obtained galena concentrate had a Pb recovery and grade of 58.36% and 83.45%, respectively. Micro-flotation experiments showed that Na2SO3 depressed the floatability of pyrite more strongly than that of galena. Moreover, the depression mechanism of Na2SO3 was observed through contact angle measurements, ultraviolet–visible spectrophotometry (UV–Vis) analysis, and time of flight secondary ion mass spectrometry (TOF-SIMS). This study provides an important reference for the depression of pyrite from a galena-pyrite mixed concentrate with low lime dosage.

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