Apparent partial loss 40Ar/39Ar age spectra of hornblende from the Palaeoproterozoic Lapland-Kola orogen (arctic European Russia): insights from numerical modelling and multi-method in-situ micro-sampling geochronology

Abstract

40Ar/39Ar age spectra with progressively increasing step ages are well known for metamorphic hornblende and have been classically interpreted by partial loss of radiogenic argon by diffusion processes during younger thermo-tectonic reworking. Application of a number of numerical modelling tools based on diffusion theory and that assume thermally activated loss of radiogenic 40Ar by solid-state volume diffusion suggests that staircase-shaped age spectra of Neoarchaean tschermakitic hornblende from the Lapland-Kola Orogen are due to argon losses of 40–50% during reheating to 450 ± 25 °C in Palaeoproterozoic time. However, in hornblende samples that yielded staircase-type age spectra, biotite occurs in the matrix, as well as intimately and abundantly intergrown with the amphibole along grain boundaries, cleavages, fractures and other defects. Drilling of 1.5 mm diameter discs from carefully selected hornblende grains in petrographic thin sections permitted to minimise the effects of contaminant biotite inclusions and/or compositional zoning of the amphibole. 40Ar/39Ar laser probe step-heating of drilled biotite-free hornblende discs yielded flat age spectra, suggesting absence of thermally activated radiogenic 40Ar loss. This would imply unrealistically contrasting temperature histories for neighbouring grains. Apparent-loss age spectra, thus, result from differential gas release of hornblende and an included, earlier degassing minor contamination of much younger biotite, which had apparently not been completely eliminated from the amphibole separate, despite careful handpicking. This is confirmed by the Ca/K ratio spectra — a proxy for 37ArCa/39ArK — of hornblende that are flat for drilled biotite-free hornblende grains, but initially low for hornblende separates. A drilled disc and a separate of hornblende from a biotite-free amphibolite did not yield apparent loss spectra, but flat age and Ca/K ratio spectra, confirming the interpretation of the role of biotite.