Abstract
ABSTRACT At T = (278.15–318.15) K and atmospheric pressure, Hepler’s constant values, (∂2 V B/∂ T 2) P , and apparent molar expansivities (E φ) were calculated using the temperature dependence of apparent molar volumes (V B). Because of the increase in hydrophobic hydration of tetramethylpiperidine 1-oxyl-based ionic liquids (TILs), the Hepler’s constant values were found to change from positive to negative, indicating that the TILs under consideration changed primarily from structure-promoting to structure-breaking. The critical micelle concentration of conductivity (CMC) was calculated based on experimental conductivity, which reflects the dissociation and the interaction and aggregation behaviour of TILs.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
