Apparent molar heat capacities and volumes of silver nitrate and silver perchlorate in aqueous solution at 298 K

Abstract

We have made calorimetric and density measurements leading to apparent molar heat capacities and volumes of dilute aqueous solutions of silver nitrate and silver perchlorate at 298 K. Resulting apparent molar properties at infinite dilution are the following: φ o c (AgNO 3) = − 36.8 J K −1 mol −1, φ o v (AgNO 3) = 29.1 cm 3 mol −1, φ o c (AgClO 4) = 11.0 J K −1 mol −1, and φ o v (AgClO 4) = 43.5 cm 3 mol −1.