Abstract
An apparatus designed to measure the specific ionic conductance of solid salts in the range 10-9 to 10-13 Ω-1 cm-1 is described. The use of a low-frequency pulse technique to avoid polarization together with the precaution of making all measurements in high vacuum, have enabled values of κ as low as 5 × 10-15 Ω-1 cm-1 to be determined. The performance of the apparatus is illustrated by the results obtained in the determination of the specific conductance of potassium and strontium azides.
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