AOPs-based remediation of petroleum hydrocarbons-contaminated soils: Efficiency, influencing factors and environmental impacts.

Abstract

Petroleum hydrocarbons are a class of anthropogenic compounds including alkanes, aromatic hydrocarbons, resins, asphaltenes and other organic matters, and soil pollution caused by petroleum hydrocarbons has drawn increasing interest in recent years. Multiple advanced oxidation processes (AOPs) are emerging to remediate petroleum hydrocarbons-contaminated soils, while very few studies have focused on the features of AOPs applied in soils. This review aims to provide an updated overview of the state of the science about the efficiency, influencing factors and environmental implications of AOPs. The key findings from this review include: 1) cyclodextrin and its derivatives can be used to synthesize targeting reagents; 2) soil organic matter (SOM), glucose and cement can activate persulfate; 3) SOM affects redox circumstance in soil and could be further developed for enhancing the catalysis effect of transition metals; 4) non-thermal plasma and wet oxidation are promising methods of AOPs to remove petroleum hydrocarbons from soil; 5) the occurrence, fate, and transformation of intermediates during the degradation of petroleum hydrocarbons in soil should be considered more. Overall, this review reveals an urgent need to develop the cost-effective remedial strategies for petroleum hydrocarbons contaminated soils, and to advance our knowledge on the generation, transport and propagation of radicals in soils.