Abstract
In the reaction of 2,4-dimethyl-2,4-heptanedihydroperoxide with 2,6-ditert-butyl-4-methyl-phenol in the presence of Co(II)/Co(III) ions, under conditions modelling the interaction of oxidized polypropylene with antioxidant, two alkylperoxycyclohexadienones are formed. At a lower relative concentration of the ROO′ radicals, there is also oxidative coupling and formation of bisphenol and stilbenequinone. A change in the composition of the reaction product due to a change in the relative proportions of reactants has also been demonstrated in a reaction carried out with tert-butyl-peroxyl. Alkylperoxycyclohexadienones thus obtained initiate the oxidation of tetralin.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
