Abstract
Magnetic investigation of monochalcogenides MeX where Me = Ce, Pr, or Nd and X = S, Se, or Te at 4°–1300°K was undertaken. Van Vleck's theory was used for describing experimental χ(T) dependences at T>500°K. It has been observed that monochalcogendies formed by the ions with an odd number of electrons exhibit an antiferromagnetic ordering near ∼10°K in contrast to the monochalcogenides formed by the ions with an even number of 4f electrons (Pr3+, Sm2+) except PrS. An attempt to evaluate the parameters of the exchange interaction using molecular field approximation was made. In order to explain the χ(T) dependences obtained at T < 100°K the approximation which included crystal-field and exchange effects simultaneously is required.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
