Abstract

The magnetic ionic liquids (MILs) are considered to open up a wide range of applications because of their magnetic and electrochromic switching. Until recently almost all magnetic ionic liquids containing tetrachloroferrate ion FeCl 4 − evidenced a paramagnetic temperature dependence of the magnetic susceptibility, with only small deviations from the Curie law at low temperatures. However, 1-ethyl-3-methylimidazolium tetrachloroferrate, Emim[FeCl 4], clearly exhibits a long-range antiferromagnetic ordering below the Neel temperature T N≈3.8 K. In addition, the shape of the magnetic ordering depends on the cooling speed, indicating that the magnetic coupling could be modified.

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