Abstract

Ultrasmall electronic devices require ultrasmall components. That’s why scientists have been working for the past few decades on electronic circuitry in which function is controlled by just a single molecule. Those molecules nearly always sport conjugated aromatic backbones because aromaticity in those molecules usually goes hand-in-hand with enhanced conductivity. But a team led by Latha Venkataraman and Luis M. Campos of Columbia University and Jeffrey B. Neaton of Lawrence Berkeley National Laboratory has shown that aromatic isn’t the only way to go: The team has demonstrated a highly conducting, reversible, single-molecule switch based on antiaromaticity (Sci. Adv. 2017, DOI: 10.1126/sciadv.aao2615). In classical organic chemistry, Hückel’s rule states that conjugated cyclic molecules with 4n+2 π electrons exhibit enhanced stability because they are aromatic. Related molecules with 4n π electrons are comparatively unstable and described as antiaromatic, a concept pioneered by Columbia’s Ronald Breslow, who died Oct. 25. Intrigued by the possibility

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