Abstract
Four complexes including [PtCl(8-OQ)](arylolefin)] (arylolefin: Eug, M1; Aceug, M2, Eteug, M3, Preug, M4) were obtained by the reaction between 8-hydroxyquinoline and K[PtCl3(arylolefin)] in high yields. The 3D structure of M1 has been determined for the first time by DFT calculation combined with the experimental NOESY spectrum. The result showed that M1 exists as distorted square-planar coordination with angles of O-Pt-Cl and N-Pt-O of 176.4o and 81.0o respectively. In which 8-OQ coordinates with Pt(II) through both the N and O atoms, Eug bonds with Pt(II) via the C=Cally and in trans position to the N atom of 8-OQ. The investigation of the biological activities of the synthesized complexes showed that they display weak anti-bacterial and antifungal activities.
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